A simple, mild elimination of hydrogen halide from primary alkyl bromides and iodides

S Jeropoulos, EH Smith

文献索引：Jeropoulos, Sotiris; Smith, Edward H. Journal of the Chemical Society, Chemical Communications, 1986 , # 21 p. 1621 - 1622

全文：HTML全文

被引用次数: 7

摘要

Addition of a solution of a primary alkyl bromide or iodide and 1, 8-diazabicyclo [5.4. 0] undec-7-ene in tetrahydrofuran (THF) to a solution prepared from dichlorobis (triphenylphosphine) nickel, triphenylphosphine, and n-butyl-lithium in THF results in an elimination at room temperature to give, in most cases, the terminal alkene.