Tetrahedron

Small ring compounds—XXX: Homolytical aromatic substitution and hydrogen abstraction reaction with cyclopropyl radical

T Shono, I Nishiguchi

文献索引：Shono,T.; Nishiguchi,I. Tetrahedron, 1974 , vol. 30, p. 2183 - 2190

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被引用次数: 20

摘要

Homolytic aromatic substitution and hydrogen abstraction reactions with cyclopropyl radical were carried out to determine the reactivity and ionic character of cyclopropyl radical by examination of the orientation effect, partial rate factor and influence of substituents. By thermal decomposition of biscyclopropaneformyl peroxide in a series of substituted benzenes, the corresponding cyclopropylated benzene derivatives (the mixture of ortho, ...