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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Pentamethylcyclopentadienide in organic synthesis: nucleophilic addition of lithium pentamethylcyclopentadienide to carbonyl compounds and carbon–carbon bond …

M Uemura, K Yagi, M Iwasaki, K Nomura, H Yorimitsu…

文献索引：Uemura, Minoru; Yagi, Kazunari; Iwasaki, Masayuki; Nomura, Kenichi; Yorimitsu, Hideki; Oshima, Koichiro Tetrahedron, 2006 , vol. 62, # 15 p. 3523 - 3535

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被引用次数: 8

摘要

Lithium pentamethylcyclopentadienide (C5Me5Li, Cp* Li) reacted with aromatic aldehyde to provide the corresponding carbinol in excellent yield. The carbinol returns to the parent aldehyde and pentamethylcyclopentadiene upon exposure to acid or due to heating. Chlorodimethylaluminum is essential as an additive to attain the nucleophilic addition of Cp* Li to aliphatic aldehyde. The carbinol derived from aliphatic aldehyde returns to the parent ...

7-hydroxy-7-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)heptanenitrile结构式

7-hydroxy-7-(1,...

~73%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

HEPTANENITRILE, 7-OXO-结构式

HEPTANENITRILE,...

10-chloro-1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-1-decanol结构式

10-chloro-1-(1,...

~96%

10-chlorodecanal结构式

10-chlorodecanal

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

7-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-7-tridecanol结构式

7-(1,2,3,4,5-pe...

~97%

7-十三酮结构式

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

(2-naphthyl)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methanol结构式

(2-naphthyl)(1,...

~85%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

2-萘甲醛结构式

(4-bromophenyl)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methanol结构式

(4-bromophenyl)...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

对溴苯甲醛结构式

对溴苯甲醛

methyl 4-[(hydroxy)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methyl]benzoate结构式

methyl 4-[(hydr...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

对甲酰基苯甲酸甲酯结构式

对甲酰基苯甲酸甲酯

(2-naphthyl)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methanol结构式

(2-naphthyl)(1,...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

2-萘甲醛结构式

{4-[(hydroxy)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methyl]phenyl}(phenyl)methanone结构式

{4-[(hydroxy)(1...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

4-苯甲酰基苯甲醛结构式

4-苯甲酰基苯甲醛

10-chloro-1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-1-decanol结构式

10-chloro-1-(1,...

~0%

10-chlorodecanal结构式

10-chlorodecanal

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-3-phenyl-1-propanol结构式

1-(1,2,3,4,5-pe...

~0%

3-苯丙醛结构式

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

1-cyclohexyl-1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-methanol结构式

1-cyclohexyl-1-...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

环己烷甲醛结构式

环己烷甲醛

methyl 6-hydroxy-6-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)hexanoate结构式

methyl 6-hydrox...

~0%

6-氧代己酸甲酯结构式

6-氧代己酸甲酯

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

7-hydroxy-7-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)heptanenitrile结构式

7-hydroxy-7-(1,...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

HEPTANENITRILE, 7-OXO-结构式

HEPTANENITRILE,...

(4-buthoxyphenyl)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methanol结构式

(4-buthoxypheny...

~0%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

4-丁氧基苯甲醛结构式

4-丁氧基苯甲醛

7-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-7-tridecanol结构式

7-(1,2,3,4,5-pe...

~99%

7-十三酮结构式

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-3-phenyl-1-propanol结构式

1-(1,2,3,4,5-pe...

~%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

methyl 6-hydroxy-6-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)hexanoate结构式

methyl 6-hydrox...

~%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

10-chloro-1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-1-decanol结构式

10-chloro-1-(1,...

~%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-1-dodecanol结构式

1-(1,2,3,4,5-pe...

~%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

7-hydroxy-7-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)heptanenitrile结构式

7-hydroxy-7-(1,...

~%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

1-cyclohexyl-1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-methanol结构式

1-cyclohexyl-1-...

~%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

1-cyclohexyl-1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-methanol结构式

1-cyclohexyl-1-...

~80%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

环己烷甲醛结构式

环己烷甲醛

(4-bromophenyl)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methanol结构式

(4-bromophenyl)...

~91%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

对溴苯甲醛结构式

对溴苯甲醛

(4-buthoxyphenyl)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methanol结构式

(4-buthoxypheny...

~99%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

4-丁氧基苯甲醛结构式

4-丁氧基苯甲醛

1-(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)-1-dodecanol结构式

1-(1,2,3,4,5-pe...

~0%

十二醛结构式

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

对溴苯甲醛结构式

对溴苯甲醛

~%

4-[hydroxy(phenyl)methyl]benzaldehyde结构式

4-[hydroxy(phen...

{4-[(hydroxy)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methyl]phenyl}(phenyl)methanone结构式

{4-[(hydroxy)(1...

~89%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

4-苯甲酰基苯甲醛结构式

4-苯甲酰基苯甲醛

methyl 4-[(hydroxy)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methyl]benzoate结构式

methyl 4-[(hydr...

~91%

1,2,3,4,5-五甲基环戊二烯结构式

1,2,3,4,5-五甲基环戊二烯

对甲酰基苯甲酸甲酯结构式

对甲酰基苯甲酸甲酯

Practical, high-yield, regioselective, rhodium-catalyzed hyd...

[Cuny, Gregory D.; Buchwald, Stephen L. Journal of the American Chemical Society, 1993 , vol. 115, # 5 p. 2066 - 2068]

Direct and chemoselective conversion of carboxylic acids int...

[Fujisawa, Tamotsu; Mori, Toshiki; Tsuge, Shoichi; Sato, Toshio Tetrahedron Letters, 1983 , vol. 24, # 14 p. 1543 - 1546]

Cerium (III) chloride-mediated reactions of sulfonamide dian...

[Johnson II, David C.; Widlanski, Theodore S. Journal of Organic Chemistry, 2003 , vol. 68, # 13 p. 5300 - 5309]

Cerium (III) chloride-mediated reactions of sulfonamide dian...

[Johnson II, David C.; Widlanski, Theodore S. Journal of Organic Chemistry, 2003 , vol. 68, # 13 p. 5300 - 5309]