Polyhedron

Isolation and X-ray structures of four Rh (PCP) complexes including a Rh (I) dioxygen complex with a short O–O bond

…, DC Grills, JC Hanson, KW Huang, JT Muckerman…

文献索引：Hayashi, Yukiko; Szalda, David J.; Grills, David C.; Hanson, Jonathan C.; Huang, Kuo-Wei; Muckerman, James T.; Fujita, Etsuko Polyhedron, 2013 , vol. 58, p. 106 - 114

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被引用次数: 2

摘要

The reaction of RhCl3· H2O with tBu2P (CH2) 5PtBu2 afforded several complexes including [RhIII (H) Cl {tBu2P (CH2) 2CH (CH2) 2PtBu2}](1),[RhIIIHCl2 {tBu2P (CH2) 5PtBu2}] 2 (2),[RhICl {tBu2P (CH2) 2CHCHCH2PtBu2}](3) and [RhICl {tBu2PCH2C (O) CHCHCH2PtBu2}](4). X-ray crystal structures of 3 and 4 showed that the CC bond on the C5 unit of tBu2P (CH2) 5PtBu2 is bound to Rh (I) in a η2 configuration. In 4, the Rh atom has ...