Tetrahedron letters

A new mode of cyclic carbamate formation via tert-butyldimethylsilyl carbamate. Stereoselective syntheses of statine and its analogue

M Sakaitani, Y Ohfune

文献索引：Sakaitani, Masahiro; Ohfune, Yasufumi Tetrahedron Letters, 1987 ,  vol. 28,  # 34  p. 3987 - 3990

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被引用次数: 32

摘要

Abstract Stereoselective construction of 1, 2-and 1, 3-amino hydroxyl systems was carried out using SN 2′(initiated by AgF or AgF-Pd (II)) cyclic carbamate formations from tert- butyldimethyl silyl carbamates. This method was applied to the syntheses of statine and AHPPA, efficiently.