(Triethylgermyl) tributylstannane reacts metal-selectively with allylic halides at room temperature (rt) in the presence of tris (dibenzylideneacetone) dipalladium, Pd2 (dba) 3CHCl3, to provide an alternative route to allylgermanes.(Dimethylphenylgermyl) tributylstannane regio-and stereoselectively reacts more readily with allylic halides than (triethylgermyl) tributylstannane affording the corresponding allylgermanes in quantitative ...
