Synthesis, Structure, and Catalytic Activity of Some New Chiral 2??Menthylindenyl and 2??Menthyl??4, 7??dimethylindenyl Rhodium Complexes

H Schumann, O Stenzel, S Dechert…

文献索引：Schumann, Herbert; Stenzel, Oleg; Dechert, Sebastian; Girgsdies, Frank; Blum, Jochanan; Gelman, Dmitri; Halterman, Ronald L. European Journal of Inorganic Chemistry, 2002 , # 1 p. 211 - 219

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被引用次数: 14

摘要

Abstract Optically active rhodium complexes containing the chiral, menthyl-substituted indenyl ligands (−)-2-menthyl-4, 7-dimethylindene and (−)-2-menthylindene are described. Metathesis reactions of the chiral lithium salts of these indenyl systems with the appropriate starting materials yielded the complexes (−)-(2-menthyl-4, 7-dimethylindenyl) Rh (CO) 2 (2),(−)-(2-menthyl-4, 7-dimethylindenyl) Rh (dppe)(3),(+)-(2-men-thylindenyl) Rh (dppe)(5) ...