Tetrahedron letters

LiAlH 4 Promoted reductive deoxygenation of hydroxybenzyl alcohols via benzoquinone methide intermediates

W Baik, HJ Lee, S Koo, BH Kim

文献索引：Baik, Woonphil; Lee, Hyun Joo; Koo, Sangho; Kim, Byeong Hyo Tetrahedron Letters, 1998 , vol. 39, # 44 p. 8125 - 8128

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被引用次数: 9

摘要

Primary and secondary hydroxybenzyl alcohols react with LiAlH4 in chlorobenzene to give the corresponding alkylphenols. The reaction proceeds through the formation of benzoquinone methide as an intermediate. An example of [4+ 2] cycloaddition of benzoquinone methide is also reported.