Journal of Organometallic Chemistry

Catalytic dehydrogenation of cyclooctane with titanium, zirconium and hafnium metallocene complexes

S Taubmann, CE Denner, HG Alt

文献索引：Taubmann, Sandra; Denner, Christine E.; Alt, Helmut G. Journal of Organometallic Chemistry, 2009 , vol. 694, # 13 p. 2005 - 2019

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被引用次数: 4

摘要

Metallocene complexes in combination with cocatalysts like methylalumoxane (MAO) are not only excellent catalysts for olefin polymerization but also appropriate catalysts for the activation of alkanes in homogeneous (autoclave) and heterogeneous (fixed bed reactor) reactions. The activities of the catalysts depend on the temperature, the cocatalysts, additives, the central metal and the ligand structure. Generally, complexes with low steric ...