Zur Biosynthese der Rubratoxine

S Nieminen, TG Payne, P Senn…

文献索引：Nieminen; Payne; Senn; Tamm Helvetica Chimica Acta, 1981 , vol. 64, # 7 p. 2162 - 2174

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被引用次数: 9

摘要

Abstract In order to check the hypothesis that rubratoxin B (2), a C 26-metabolite, is formed biogenetically by head-to-tail coupling of two identical C 13-precursors derived from decanoic acid and oxaloacetic acid, two labelled forms of the postulated C 13-intermediate 2- ((E)-1'-octenyl)-3-[14 C] methyl-and 2-((E)-1'-octenyl)-3-[13 C]-methylmaleic anhydride (10), were synthesized. The labelled compounds 10 as well as a number of other 14 C]-and [13 ...