Nucleophilic Substitution with Phosphide Anions Prepared by an Action of Sodium Dihydridobis (2-methoxyethanolato) aluminate on Phosphorus Compounds

M Yamashita, N Suzuki, M Yamada, Y Soeda…

文献索引：Yamashita, Mitsuji; Suzuki, Nobuyoshi; Yamada, Manabu; Soeda, Yukio; Yamashita, Hiroaki; et al. Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 1 p. 219 - 222

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被引用次数: 8

摘要

Phosphide anions, prepared by an action of sodium dihydridobis (2-methoxyethanolato) aluminate on derivatives of phosphine, phosphine oxide, or phosphorus esters, react with primary and secondary alkyl halides to produce phosphine derivatives having a newly formed phosphorus-carbon bond. The reactivity increases in the order of chloride< bromide< iodide and of secondary< primary in alkyl halide. Reaction of phosphide anion is also ...