Investigations of the nature of dehydrogenation of the. alpha.-carbon atom in the oxidation of amines coordinated to ruthenium

FR Keene, MJ Ridd, MR Snow

文献索引：Keene, F. Richard; Ridd, Michael J.; Snow, Michael R. Journal of the American Chemical Society, 1983 , vol. 105, # 24 p. 7075 - 7081

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被引用次数: 57

摘要

Abstract: The oxidations of the amine complexes R u (~~~)~(AB)~+(where AB= ampy [2- (aminomethyl) pyridine], d2-ampy [2-(1, l-dideuterioaminomethyl) pyridine], and Meampy [2- (1-aminoethy1) pyridinel and bpy= 2, 2'-bipyridine) in aqueous solution to the corresponding imine species have been studied by using flash photolysis techniques. The rate-determining step of the reaction involves removal of a hydrogen from the a-carbon atom and the ...