An unexpected sialylation: Total syntheses of ganglioside GM4 and a positional isomer

J Gervay, JM Peterson, T Oriyama…

文献索引：Journal of Organic Chemistry, , vol. 58, # 20 p. 5465 - 5468

全文：HTML全文

被引用次数: 38

摘要

... Chem., Vol. ... precursor 3 by a glycal epoxide constitutes a major simplification in ganglioside synthesis in that it avoids the need for a multistep installation of a directing group at c-2. BY Permuting the timing of sialylation and ceramide introduction, this chemistry could be ... J. Org. ...