Tetrahedron

Theoretical and experimental study on the reactivity of methyl dichlorobenzoates with sulfur-centered nucleophiles by electron transfer reactions

JG Uranga, JP Montañez, AN Santiago

文献索引：Uranga, Jorge G.; Montanez, Juan P.; Santiago, Ana N. Tetrahedron, 2012 , vol. 68, # 2 p. 584 - 589

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被引用次数: 3

摘要

Reactions of methyl 2, 5-dichlorobenzoate or methyl 3, 6-dichloro-2-methoxybenzoate with sulfur-centered nucleophiles gave mono-and disubstitution products, respectively through SRN1 mechanism in liquid ammonia. Products obtained could be potential herbicides less toxic to the environment. Theoretical studies explained the reactivity observed considering geometries, and spin densities of radical anions and potential energy surfaces for the ...