Organic letters

Olefin cross-metathesis reactions at room temperature using the nonionic amphiphile “PTS”: Just add water

…, GT Aguinaldo, S Ghorai, K Voigtritter

文献索引：Lipshutz, Bruce H.; Aguinaldo, Grant T.; Ghorai, Subir; Voigtritter, Karl Organic Letters, 2008 , vol. 10, # 7 p. 1325 - 1328

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被引用次数: 111

摘要

The first examples of unsymmetrical olefin cross-metathesis reactions in water, involving water-insoluble substrates, at room temperature and using commercially available catalysts are reported. The key to success is to include small percentages of the nonionic, vitamin E- based amphiphile “PTS”. The nanometer micelles formed accommodate water-insoluble substrates, along with a readily available Ru-based metathesis catalyst. Reactions ...