Transition metal reactions of silanes II. The reaction of cycloalkenes with various hydrosilanes and carbon monoxide catalyzed by Co2 (CO) 8

Y Seki, A Hidaka, S Makino, S Murai…

文献索引：Seki,Y. et al. Journal of Organometallic Chemistry, 1977 , vol. 140, p. 361 - 378

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被引用次数: 21

摘要

Abstract The reaction of cycloalkenes (cyclopentene, cyclohexene, cycloheptene, cyclooctene, 1-methylcyclohexene, and norbornene) with Et 2 MeSiH and carbon monoxide in the presence of Co 2 (CO) 8 gave the corresponding diethylmethylsiloxymethylenecycloalkenes. In such reactions of cyclohexene, the following hydrosilanes gave the corresponding siloxymethylenecyclohexanes: Me 3 SiH, EtMe 2 ...