Pyridinio??isoalloxazinophanes as Model Systems for Active??Site Complexes in Flavoenzymes: Syntheses, X??Ray Structure Analyses and Spectroscopic Properties

…, MF Zipplies, T Müller, M Storch, C Krieger

文献索引：Staab, Heinz A.; Zipplies, Matthias F.; Mueller, Thomas; Storch, Matthias; Krieger, Claus Chemische Berichte, 1994 , vol. 127, # 9 p. 1667 - 1680

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被引用次数: 10

摘要

Abstract As model systems for active site complexes in flavoenzymes, flavin and nicotinamide analogues were linked together in cyclophane skeletons of specific sterical structures. Elaborating this concept, we prepared [4] metacyclo [3](10, 6) isoalloxazinophane (3),[4](3, 1) pyridino [3](10, 6) isoalloxazinophane (4), as well as the 16-methoxycarbonyl and the 16-carboxylato derivatives (2 and 34, resp.), of 4 by multistep syntheses. For the ...