Synthesis, crystal structure and electrochemical properties of [NBu 4][Ni (mdt) 2]: a potential precursor for new materials (mdt= 1, 3-dithiole-4, 5-dithiolate)
…, N Veldman, AL Spek, P Cassoux, R Carlier…
文献索引：Veldhuizen, Yvonne S. J.; Veldman, Nora; Spek, Anthony L.; Cassoux, Patrick; Carlier, Roger; Mulder, Martijn J. J.; Haasnoot, Jaap G.; Reedijk, Jan Journal of the Chemical Society - Dalton Transactions, 1998 , # 18 p. 2989 - 2993
Reaction of methylenedithio-1, 3-dithiol-2-one with sodium methanolate resulted in the anionic ligand mdt2–(mdt= 1, 3-dithiole-4, 5-dithiolate) which has been co-ordinated to nickel. The salt [NBu4][Ni (mdt) 2] was successfully crystallised and its crystal structure showed that the Ni (mdt) 2 unit is significantly distorted from planarity. Electrochemical studies showed that [NBu4][Ni (mdt) 2] can be further oxidised in two steps via the neutral [ ...
