Abstract Thioreductones and Derivatives. Replacement of one or two (principally also three) O-atoms in aci-reductones by sulfur leads to the corresponding thioreductones. In the present paper, different methods of their synthesis are discussed. Substitution of the bromo nucleofug in the 2-position of 1, 3-dicarbonyl compounds as well as of a 3-oxosulfone by selected sulfur nucleophiles is assumed to follow an S RN 1 pathway. Characteristic ...
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