The Formation of Cyclopropanes by the Rearrangement of 4-Benzoyloxycycloalkanones

P Yates, CD Anderson

文献索引：Yates; Anderson Journal of the American Chemical Society, 1958 , vol. 80, p. 1264 Journal of the American Chemical Society, 1963 , vol. 85, p. 2937,2941

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被引用次数: 15

摘要

During the course of experiments concerned with the Stobbe condensation of 4- benzoyloxycycloheptanone (I), it was discovered that I rearranges to an isomeric keto acid on treatment with potassium 1-butoxide. This keto acid was not obtained in crystalline form but was characterized by its conversion to a semicarbazone and by the formation of the 2, 4- dinitrophenylhydrazones of its ethyl and methyl esters by treatment with 2, 4- ...