Tetrahedron

Preparation of chiral phosphorus, sulfur and selenium containing 2-aryloxazolines

…, M Kiefer, T Langer, H Rieck, H Schell, P Sennhenn…

文献索引：Peer, Markus; De Jong, Johannes C.; Kiefer, Matthias; Langer, Thomas; Rieck, Heiko; Schell, Heico; Sennhenn, Peter; Sprinz, Juergen; Steinhagen, Henning; Wiese, Burkhard; Helmchen, Guenter Tetrahedron, 1996 , vol. 52, # 21 p. 7547 - 7583

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被引用次数: 2

摘要

A series of enantiomerically pure 2-[2-(diarylphosphino) aryl]-oxazolines was prepared from commercially available or synthetic amino alcohols. For oxazoline formation three procedures were employed:(i) one pot condensation with a 2-halobenzoic acid,(ii) ZnCl2 catalyzed condensation with a 2-halobenzonit-rile, and (iii) a three step sequence via a 2- halobenzamide and a tosylate or chloride. Phosphinooxazolines containing stereogenic ...