Electronic excitation energy partitioning in dissymmetric dioxetane thermolyses. The absolute chemiluminescence yields and triplet to singlet excited state ratios for 3- …
KA Horn, GB Schuster
文献索引：Horn,K.A.; Schuster,G.B. Journal of the American Chemical Society, 1978 , vol. 100, # 21 p. 6649 - 6656
23, 408 (1978); J. Polym. Sci., Polym. Lett. Ed., 16, 335 (1978). on a single sample preannealed for 14 h at 333 K [gt)-0.032; T,,,-375 K]. They incorrectly concluded that this indicated the presence of a" new high temperature phase which acts as the monomer form for the bulk of the reaction". This is clearly not the case since T,,, increases monotonically with conversion. This increase is undoubtedly a consequence of the fact that there is solid ...
