Tetrahedron letters

Palladium-catalyzed asymmetric alkoxycarbonylation of allyl phosphates

Y Imada, M Fujii, Y Kubota, SI Murahashi

文献索引：Imada, Yasushi; Fujii, Masaru; Kubota, Yasushi; Murahashi, Shun-Ichi Tetrahedron Letters, 1997 , vol. 38, # 47 p. 8227 - 8230

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被引用次数: 19

摘要

Palladium-catalyzed alkoxycarbonylation of allyl phosphates proceeds with high efficiency affording the corresponding β, γ-unsaturated esters stereoselectively with inversion of configuration at the allylic carbon center. Palladium complexes bearing chiral monodentate phoshine ligands are effective catalysts for asymmetric allylic carbonylation of cyclohex-2-en- 1-yl phosphates 1 to give optically active cyclohex-2-ene-1-carboxylates 2 in moderate ...