Bulletin of the Chemical Society of Japan

The Dehydration Reactions of Nitroparaffins and Aldoximes

T Mukaiyama, T Hata

文献索引：Mukaiyama,T.; Hata,T. Bulletin of the Chemical Society of Japan, 1960 , vol. 33, p. 1382 - 1386

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被引用次数: 8

摘要

This reaction proceeds to the formation of disubstituted urea and furoxane through intermediates or amine and nitrile oxide which are formed by-the decomposition of the addition compound of isocyanate and aci-nitroparaffin with spontaneous evolution of carbon dioxide. The reaction of the amine with isocyanate yields di-substituted urea and furoxane is formed by the dimerization of nitrile oxide. Nitrite oxide, one of the two intermediates, was ...