Methyl fluorosulphonyldifluoroacetate; a new trifluoromethylating agent

QY Chen, SW Wu

文献索引：Chen, Qing-Yun; Wu, Sheng-Wen Journal of the Chemical Society, Chemical Communications, 1989 , # 11 p. 705 - 706

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被引用次数: 119

摘要

Methyl fluorosulphonyldifluoroacetate, in the presence of copper(1) iodide, is used as the source of trifluoromethyl group which replaces the halogen in aryl, alkenyl, and alkyl halides. ... Recently, considerable attention has been devoted to finding novel methods for introducing the trifluoromethyl group into organic compounds because of increasing demands in medi- cine and biochemistry.' During the course of our investigation into difluorocarbene chemistry2 ...