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Tetrahedron

A reinvestigated mechanism of ribosylation of adenine under silylating conditions

G Framski, Z Gdaniec, M Gdaniec, J Boryski

文献索引:Framski, Grzegorz; Gdaniec, Zofia; Gdaniec, Maria; Boryski, Jerzy Tetrahedron, 2006 , vol. 62, # 43 p. 10123 - 10129

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被引用次数: 18

摘要

The mechanism of chemical synthesis of adenosine has been reinvestigated. Depending on the reaction conditions and the presence of N6-protecting groups, ribosylation of adenine proceeds via different kinetic products: 3-riboadenine in strongly acidic media, 7-ribosylated derivative in the silyl method, and 1-(β-d-ribofuranosyl) adenine when applying N6- acyladenine and silylating conditions.