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Iodosobenzene diacetate, an efficient reagent for the oxidative decarboxylation of carboxylic acids

JI Concepcion, CG Francisco, R Freire…

文献索引:Concepcion, J. I.; Francisco, C. G.; Freire, R.; Hernandez, R.; Salazar, J. A.; Suarez, E. Journal of Organic Chemistry, 1986 , vol. 51, # 3 p. 402 - 404

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被引用次数: 103

摘要

Particularly, iododecarboxylation of carboxylic acids to alkyl iodides has been effected by reaction of the free acid with tert-butyl hypoiodite2avb or with combinations of LTA2a, b or mercuric oxidezc with iodine and also treating the silver carboxylate with iodine. 2d It is known that several other oxidizing metal ions such as CeN, Mnm, Corn, and T1"'can also effect the decarboxylation of We have recently reported4 the functionalization of ...