Supernucleophilic systems based on functionalized surfactants in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids: I. Reactivity of a …
Abstract A new functionalized gemini surfactant, 3, 3′-[2-(hydroxyimino) propane-1, 3-diyl] bis (1-dodecyl-1 H-imidazol-3-ium) dichloride, and its non-micelle-forming methyl analog, were synthesized. Nucleophilicity of the oximate group in these compounds in the decomposition of 4-nitrophenyl esters derived from phosphorus and sulfur acids follows Brønsted relations for monomeric functionalized surfactants and non-micelle-forming ...