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2, 2-Dimethyl-1-(2, 4, 6-trinitrophenyl) hydrazine

JW Quail, JA Weil, MP Singh

文献索引:Quail, J. Wilson; Weil, John A.; Singh, Malvinder P. Acta Crystallographica Section C: Crystal Structure Communications, 2000 , vol. 56, # 2 p. 235 - 236

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被引用次数: 4

摘要

The title molecule (DMPH-H), C8H9N5O6, was investigated to provide comparison with 2, 2- diphenyl-1-picrylhydrazine, which unlike DMPH-H is readily oxidizable to form a well known stable free radical (DPPH). The structure shows essential differences in the configuration of the hydrazine-N atoms, the ortho-nitro group orientations and the crystal packing. The bond angles of the dimethylamino N atom [107.90 (13), 108.96 (12) and 112.21 (13)°] are ...