Heterogeneous Palladium??Catalyzed Synthesis of Aromatic Ethers by Solvent??Free Dehydrogenative Aromatization: Mechanism, Scope, and Limitations Under …
M Sutter, R Lafon, Y Raoul, E Métay…
文献索引：Sutter, Marc; Lafon, Romain; Raoul, Yann; Metay, Estelle; Lemaire, Marc European Journal of Organic Chemistry, 2013 , # 26 p. 5902 - 5916
Abstract Starting from cyclohexanone derivatives and alcohols, both non-aromatic precursors, aryl ethers could be synthesized in good yields and with good selectivities in the presence of a catalytic amount of Pd/C, in one step, without added solvent, in a reaction vessel open to air. For less reactive substrates, the addition of 1-octene in a closed system under non-aerobic conditions improved the conversion. In addition, the catalyst could be ...
