. ALPHA.-Fluorination of Methyl Phenyl Sulfoxide and Related Compounds by Molecular Fluorine: A Novel Method for the Introduction of Fluorine into Sulfoxides …

A TOYOTA, Y ONO, J CHIBA, T SUGIHARA…

文献索引：Toyota, Akemi; Ono, Yoshinori; Chiba, Jun; Sugihara, Takumichi; Kaneko, Chikara Chemical and Pharmaceutical Bulletin, 1996 , vol. 44, # 4 p. 703 - 708

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被引用次数: 26

摘要

Direct formation of α-fluorosulfones from sulfoxides bearing α-H atoms merely by reaction with molecular fluorine (5% F 2/N 2) is reported, and a novel non-Pummerer-type mechanism is proposed for this α-fluorination reaction.