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Preparation of 3', 4'-Dihydroxy-6-carboxyflavonol

T Nagano, K Matsumura

文献索引:Nagano; Matsumura Journal of the American Chemical Society, 1953 , vol. 75, p. 6237

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被引用次数: 10

摘要

The oxime I1 of 2-hydroxy-5-carboxyacetophe-none, on Beckmann rearrangement with sulfuric acid, produced a mixture of 3-acetamino-4-hydroxybenzoic acid and 2-methyl-5- carboxybenzoxazole. Thus the configuration of the oxime is cis with respect to the methyl, assuming that spacial isomerization did not take place during the treatment.