Organic chemistry of dichlorosilane. Additions to conjugated and unconjugated diene systems followed by intramolecular cyclizations

RA Benkeser, EC Mozdzen, WC Muench…

文献索引：Benkeser,R.A. et al. Journal of Organic Chemistry, 1979 , vol. 44, p. 1370 - 1376

被引用次数: 25

摘要

The addition of dichlorosilane to both conjugated and unconjugated dienes was studied in the presence of chloroplatinic acid as a catalyst. The mode of addition to conjugated dienes was predominantly by a 1, 4 pathway. With unconjugated dienes, addition to a terminal double bond was much faster than to internal double bonds and hence provided a convenient method for the synthesis of alkenyldichlorosilanes. The latter were cyclized in ...