前往化源商城

Journal of Chemical & Engineering Data

Parallel NMR Based on Solution Magnetic-Susceptibility Differences. Application to Isotopic Effects on Self-Diffusion†

PH Fries, D Imbert

文献索引:Fries, Pascal H.; Imbert, Daniel Journal of Chemical and Engineering Data, 2010 , vol. 55, # 5 p. 2048 - 2054

全文:HTML全文

被引用次数: 4

摘要

Different susceptibility NMR line shifts can be induced in distinct liquid solutions by dissolving different concentrations of complexes of paramagnetic lanthanide Ln3+ ions. We show how these solutions, put in capillaries, can be simultaneously studied with a standard high-resolution spectrometer. After theoretical justification the method is illustrated by an investigation of the effects of H/D substitution on self-diffusion in heavy water. Non- ...