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Highly twisted helical polyacetylene with morphology free from the bundle of fibrils synthesized in chiral nematic liquid crystal reaction field

M Goh, M Kyotani, K Akagi

文献索引:Goh, Munju; Kyotani, Mutsumasa; Akagi, Kazuo Journal of the American Chemical Society, 2007 , vol. 129, # 27 p. 8519 - 8527

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被引用次数: 80

摘要

We synthesized novel axially chiral binaphthyl derivatives with highly twisting powers by substituting phenylcyclohexyl (PCH) mesogenic moieties into 2, 2'positions or 2, 2', 6, 6'positions of binaphthyl rings. The di-and tetrasubstituted binaphthyl derivatives, abbreviated as D-1 and D-2, respectively, were adopted as chiral dopants to induce chiral nematic liquid crystals (N*-LCs) available for synthesis of helical polyacetylene. The ...