Rhodium??Catalyzed Reaction of 1??Alkenylboronates with Aldehydes Leading to Allylation Products

…, T Igarashi, T Miura, M Murakami

文献索引：Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469

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被引用次数: 15

摘要

The allylation reaction of carbonyl compounds with gsubstituted allylboron reagents is one of the most reliable procedures for the regio-and diastereoselective synthesis of homoallylic alcohols, and hence, is widely used in organic synthesis.[1] As the stereochemistry of the CÀC double bond of the substituted allylboron reagent dictates the stereochemistry of the resultant homoallylic alcohols, it is crucial to obtain stereochemically defined g-substituted ...