Journal of Organometallic Chemistry

Facile formation of the cycloheptatrienyl trianion by lanthanide and actinide ions

JT Miller, CW Dekock

文献索引：Miller, Jeffrey T.; Dekock, Carroll W. Journal of Organometallic Chemistry, 1981 , vol. 216, # 1 p. 39 - 48

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被引用次数: 16

摘要

Abstract In addition of lithium cycloheptadienide (LiC 7 H 8 R; R= hydrogen, methyl and n- butyl) to lanthanide and actinide chlorides results in the facile formation of the cycloheptatrienyl trianion complexed to the metal ion. Characterization of the ten-π-electron aromatic cycloheptatrienyl trianion (C 7 H 6 R 3-) was made by identification of the organic products resulting from chemical reaction of the coordinated ligand, for example, ...