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Micellar dediazoniation: dramatic directive effects on the course of reaction

RA Moss, FM Dix, L Romsted

文献索引:Moss, Robert A.; Dix, Frank M.; Romsted, Laurence Journal of the American Chemical Society, 1982 , vol. 104, # 19 p. 5048 - 5050

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被引用次数: 14

摘要

Abstract: Rate constants and products are reported for the dediazoniation reactions of nonmicellar (p-diazoniobenzy1) trimethylammonium dibromide and micellar (p- diazoniobenzy1) dimethyl-n-hexadecylammonium dibromide in aqueous solutions at pH 4, 23 OC, in the presence of various concentrations of bromide ion. Rate constants for the nonmicellar (k-6 X 10" sI) and micellar (k-sI) dediazoniations were independent of ...