N-Nitroso-and N-nitrotrialkylureas and their decomposition

…, TJ Ryan, BS Hahn, RH Erickson

文献索引：White, Emil H.; Ryan, Thomas J.; Hahn, Bo Sup; Erickson, Ronald H. Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4860 - 4866

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被引用次数: 8

摘要

The synthesis and decomposition of N-(n-butyl)-N', N'-dimethyl-N-nitrosourea (2a), N-(n- butyl)-N', N'-dimethyl-N-nitrourea (3a), N', N'-dimethyl-N-(1-norborny1)-N-nitrosourea (2b), and N',"-dimethyl-N-(1-norborny1)-N-nitrourea (3b) are described. Several of the compounds show complex NMR spectra ascribable to rotational isomerism. Decomposition of 2a and 3a gave n-butyl N, N-dimethylcarbamate and tetramethylurea, while ...