The Journal of Physical Chemistry

Reactivities of chlorine atoms and peroxyl radicals formed in the radiolysis of dichloromethane

ZB Alfassi, S Mosseri, P Neta

文献索引：Alfassi, Z. B.; Mosseri, S.; Neta, P. Journal of Physical Chemistry, 1989 , vol. 93, # 4 p. 1380 - 1385

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被引用次数: 80

摘要

Radiolysis of dichloromethane (DCM) leads to formation of primary oxidizing radicals and carbon-centered radicals. The latter react with oxygen to yield peroxyl radicals. The yields and chemical behavior of these intermediates were studied by pulse radiolysis of DCM solutions containing various solutes: phenols, anilines, dimethoxybenzene, hexamethylbenzene, cyclohexene, dimethyl sulfoxide, and zinc tetratolylporphyrin. At low ...