Organic Letters

Critical role of catalysts and boranes for controlling the regioselectivity in the rhodium-catalyzed hydroboration of fluoroolefins

PV Ramachandran, MP Jennings, HC Brown

文献索引：Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C. Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402

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被引用次数: 60

摘要

Catalytic hydroboration of perfluoroalkylethylenes (RFCH CH2) with cationic and neutral rhodium complexes allows for selective access to either regioisomeric alcohol after hydroboration with catechol-and pinacolboranes, followed by oxidation with alkaline hydrogen peroxide.