Macromolecules

Propagation rate of the cationic polymerization of 2, 4, 6-trimethylstyrene: A linear free energy approach

H Mayr, AR Ofial, H Schimmel

文献索引：Zwegers,J.; Marechal,E. Bulletin de la Societe Chimique de France, 1972 , p. 1157 - 1169

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被引用次数: 13

摘要

... substituents of the benzhydrylium ions affected ΔH ⧧ whereas ΔS ⧧ remained almost constant (−117 ± 7 J mol -1 K ... A plot of log k 20 ° C vs the electrophilicity parameters E of the benzhydrylium ions ... Addition of >3 equiv of 2-chloropropene to solutions of 6−GaCl 4 or 7−GaCl 4 ...