Synthesis of disilylmethanes and polysilacarbosilanes, precursors of silicon carbide-based materials

…, P Lapouyade, P Gerval, C Biran, J Dunoguès

文献索引：Bacque, Eric; Birot, Marc; Pillot, Jean-Paul; Lapouyade, Paulette; Gerval, Pierre; Biran, Claude; Dunogues, Jacques Journal of Organometallic Chemistry, 1996 , vol. 521, # 1-2 p. 99 - 107

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被引用次数: 13

摘要

Using a new procedure, substituted disilylmethanes have been prepared from chlorosilanes, dichloromethane, and magnesium in tetrahydrofuran. Bis (chlorosilyl) methanes can be used as comonomers for the synthesis of polysilacarbosilanes, which are transformed into polycarbosilanes, precursors of silicon carbide.