The Journal of Organic Chemistry

A convenient method for utilizing the allyl grignard reagent

MP Dreyfuss

文献索引：Dreyfuss,M.P. Journal of Organic Chemistry, 1963 , vol. 28, p. 3269 - 3272

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被引用次数: 41

摘要

It is the purpose of this paper to point out and emphasize a convenient synthetic technique which has been known for a number of years but has been overlooked and even discouraged. The method of utilizing the allyl Grignard reagent reported here has been referred to as the Barbier-Grignard procedure. In this procedure the organomagnesium compound is not formed as an intermediate in the presence of an excess of carbonyl ...