Kinetics and mechanism of the atmospheric oxidation of tertiary amyl methyl ether

…, CD McIver, TE Kleindienst

文献索引：Smith, D. F.; Mciver, C. D.; Kleindienst, T. E. International Journal of Chemical Kinetics, 1995 , vol. 27, # 5 p. 453 - 472

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被引用次数: 56

摘要

Abstract Tertiary-amyl methyl ether (TAME) is proposed for use as an additive to increase the oxygen content of gasoline as stipulated in the 1990 Clean Air Amendments. The present experiments have been performed to examine the kinetics and mechanisms of the atmospheric removal of TAME. The kinetics of the reaction of OH with TAME was examined by using a relative rate technique in which photolysis of methyl nitrite or nitrous acid was ...