Tetrahedron letters

Asymmetric dihydroxylation of geranyl, neryl and trans, trans-farnesyl acetates

G Vidari, A Dapiaggi, G Zanoni, L Garlaschelli

文献索引：Vidari, Giovanni; Dapiaggi, Antonella; Zanoni, Giuseppe; Garlaschelli, Luigi Tetrahedron Letters, 1993 , vol. 34, # 40 p. 6485 - 6488

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被引用次数: 67

摘要

Abstract The asymmetric dihydroxylation of geranyl acetate, neryl acetate and trans, trans- farnesyl acetate was studied using the new Sharpless' ligands (DHQD) 2-PHAL and (DHQ) 2-PHAL. High enantioselectivity was always observed. High positional selectivity for the 6, 7- olefin was observed in the case of the monoterpene acetates.