The Journal of Physical Chemistry

Hydrogen-Bonding-Induced Electron Transfer from Triplet N, N-Dialkyl-1-naphthylamines to Benzophenone via Triplet Exciplexes 1

T Kiyota, M Yamaji, H Shizuka

文献索引：Kiyota, Tatsuya; Yamaji, Minoru; Shizuka, Haruo Journal of Physical Chemistry, 1996 , vol. 100, # 2 p. 672 - 679

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被引用次数: 46

摘要

Laser flash photolysis studies at 355-nm on the photoreactions of the benzophenone (BP) and N, N-dialkyl-1-naphthylamine, DANA (N, N-dimethyl-1-naphthylamine, DMNA, and N, N- diethyl-1-naphthylamine, DENA) system have been carried out with and without H2O and methanol in acetonitrile (ACN) at 295 K. In the nanosecond time scale, triplet energy transfer from triplet BP (3BP*) to DANA occurs with the efficiency ϕTET (0.74 for DMNA and 0.61 ...