The Halonium Ion??Mediated C C Bond Cleavage of Cyclohexene??Fused Isoxazoline N??Oxides

MJ Raihan, V Kavala, QZ Guan, CW Kuo…

文献索引：Raihan, Mustafa J.; Kavala, Veerababurao; Habib, Pateliya Mujjamil; Guan, Qiao-Zhi; Kuo, Chun-Wei; Yao, Ching-Fa Journal of Organic Chemistry, 2011 , vol. 76, # 2 p. 424 - 434

全文：HTML全文

被引用次数: 8

摘要

Abstract A protocol for the N-bromosuccinimide (NBS)-and trichloroisocyanuric acid (TCCA)- mediated cleavage of the C [BOND] C bond of isoxazoline N-oxides, fused with a cyclohexene ring, leading to the production of a long-chain diketo-halo-nitrile skeleton is described. The conversion occurs via the formation of a nitric oxide intermediate.