Intramolecular competition experiments on sulphide vs. thiocarbonyl oxidation. Evidence for electronic and steric deactivation of thiocarbonyl groups

E Schaumann, B Lange, K Reinholdt

文献索引：Schaumann, Ernst; Lange, Bettina; Reinholdt, Karin Journal of the Chemical Society, Chemical Communications, 1983 , # 15 p. 797 - 798

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被引用次数: 3

摘要

Oxidation by hydrogen peroxide or peracids to give S-oxides is a characteristic reaction of sulphides and thiocarbonyl compounds.1~2 Relatively little is known, however, about the relative ease of oxidation of a sulphide and a thiocarbonyl sulphur in the same molecule. If the two groups interact by resonance as in dithiocarboxylates2 or in thia~anthione,~ the ... Published on 01 January 1983. Downloaded by google on 16/02/2016 09:17:33. ... View Article Online / ...