Observation of intermediates during the reaction of linear alkanesulfinyl chlorides with activated zerovalent zinc

F Freeman, CN Angeletakis…

文献索引：Freeman, Fillmore; Angeletakis, Christos N.; Keindl, Monica C. Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 454 - 458

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被引用次数: 6

摘要

Methane-(2), ethane-(3), propane-(4), butane-(5), pentane-(6), hexane-(7), octane-(8), and dodecanesulfiiyl chloride (9) reacted with activated zerovalent zinc to give the corresponding alkanesulfonothioic S-alkyl esters (12-19) in 40-89% yield. The reaction of methanesulfinyl chloride (2) with activated zerovalent zinc under nitrogen in anhydrous diethyl ether at-30,-20, and 0" C was investigated by'H NMR and 13C NMR spectroscopy. ...